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Stable Palladium(0), Palladium(II), and Platinum(II) Complexes Containing a New, Multifunctional and Hemilabile Phosphino−Imino−Pyridyl Ligand: Synthesis, Characterization, and Reactivity

✍ Scribed by Rülke, Richard E.; Kaasjager, Vincent E.; Wehman, Petra; Elsevier, Cornelis J.; van Leeuwen, Piet W. N. M.; Vrieze, Kees; Fraanje, Jan; Goubitz, Kees; Spek, Anthony L.

Book ID
126804387
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
315 KB
Volume
15
Category
Article
ISSN
0276-7333

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New neutral organometallic palladium(II) complexes, obtained upon treating complexes of the type [PdRX(P ʝ N)] with PPh 3 and AgCF 3 SO 3 and consist predominantly of the [PdPhI(PNMe 2 )] (1), [PdPhI(PC=NMe)] (2), [PdPhI(PC=NEt)] (3), and [PdMeCl(PNMe 2 )] (4), {PNMe 2 means N,N-dimethyl-trans-P,P i