✦ LIBER ✦

Stable Osmium Hydrido−Carbene Complexes with CH 2 and Secondary Carbenes CHR as Ligands

✍ Scribed by Werner, Helmut; Stüer, Wolfram; Laubender, Matthias; Lehmann, Christopher; Herbst-Irmer, Regine

Book ID: 126158868
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 173 KB
Volume: 16
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om970139r

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Transition-metal complexes with sulfur l

Transition-metal complexes with sulfur ligands. 89. Unexpected formation of the highly stable binuclear nickel carbene complex [Ni(S2C)]2 from nickel(II) salts, diamine-dithiolate ligands, and C1 components [S2C2- = 1,3-imidazolidine-1,3-diylbis(2-benzenethiolate)(2-)]

✍ Sellmann, Dieter; Prechtel, Werner; Knoch, Falk; Moll, Matthias 📂 Article 📅 1992 🏛 American Chemical Society 🌐 English ⚖ 423 KB

The first palladium(0) complex with only

The first palladium(0) complex with only secondary phosphines as ligands and its oxidative-addition reactions with dichloromethane and chloroform, giving the thermally stable derivatives trans-[PdCl(R)(PBu-tert2H)2] (R = CH2Cl, CHCl2)

✍ Leoni, Piero 📂 Article 📅 1993 🏛 American Chemical Society 🌐 English ⚖ 351 KB

Carbenerhodium Complexes with Diaryl- an

Carbenerhodium Complexes with Diaryl- and Aryl(alkyl)carbenes as Ligands: The Missing Link in the Series of the Double Bond Systems trans-[RhCl{ C(C)nRR′}(L)2] Where n 0, 1, and 2

✍ Dipl.-Chem. Peter Schwab; Dipl.-Chem. Norbert Mahr; Dr. Justin Wolf; Prof. Dr. H 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 390 KB 👁 1 views

Chemistry of polynuclear metal complexes

Chemistry of polynuclear metal complexes with bridging carbene or carbene ligands. Part 108. Synthesis and reactions of the alkylidynetungsten complexes [W(?CR)(CO)2{(F3B)C(pz)3}](R = Me or C6H4Me-4, pz = pyrazol-1-yl) and their use as reagents for preparing di-and tri-metal compounds

✍ Byers, Peter K.; Stone, F. Gordon A. 📂 Article 📅 1991 🏛 The Royal Society of Chemistry 🌐 English ⚖ 928 KB

Reactions of (Chloromethyl)platinum(II)

Reactions of (Chloromethyl)platinum(II) Derivatives with Nucleophiles. Formation of (Dimethylamino)carbene Complexes Using N,N,N ‘ ,N ‘ -Tetramethylmethanediamine as Nucleophile and the X-ray Crystal and Molecular Structures of cis -[(Ph 3 P)Pt(CH 2 NMe 3 )Cl 2 ], cis ( C,P )-[(Ph 3 P)Pt(CH 2 CH 2 C(O)NMe 2 )Cl], and trans ( As,CH 2 ) -[(Ph 3 As)Pt(CHNMe 2 )(CH 2 NHMe 2 )Cl]PF 6

✍ Ferguson, George; Li, Yiwei; McAlees, Alan J.; McCrindle, Robert; Xiang, Ke 📂 Article 📅 1999 🏛 American Chemical Society 🌐 English ⚖ 209 KB

Addition of small molecules to (.eta.-C5

Addition of small molecules to (.eta.-C5H5)2Rh2(CO)(CF3C2CF3). 6. Formation of the .mu.-alkylidene complexes (.eta.-C5H5)2Rh2(.mu.-CO)(.mu.-CHR)(.mu.-CF3C2CF3) (R = CO2Et, SiMe3, CF3, or CH:CH4) and coupling reactions of the alkyne and carbene ligands within these complexes. X-ray crystal structure of (.eta.-C5H5)2Rh2(CO){C(CF3)C(CF3)CH(CO2Et)}

✍ Dickson, Ron S.; Fallon, Gary D.; Jenkins, Susan M.; Nesbit, Rhonda J. 📂 Article 📅 1987 🏛 American Chemical Society 🌐 English ⚖ 944 KB