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Stable ortho- and para-naphthaquinone methides

✍ Scribed by Keith S. Brown Jr; Paul M. Baker

Book ID
104248144
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
241 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis

In the preoedlng oouunloatlon (11, we have deuorlbed the lrolatlon and oharaoterlzation of 8ome unumal @none methlde8 (I,II,III) related to three 1,3,8-trlhydroqmaphthalene derivative8 (IV,V,VI) rhloh are present a8 their 8-gluoo8lde8 In the lnrreot Auhls nerla Fonsoolombe. The8e methlder oould be synthe8laed by the faolle oonden8atlan of the naphthalene-trio18 with blabetyl In weakly alkaline medium, and uore 8table t0 light,alr, 8Illoa or Florlrll OhrOulatO@8phj, aQUeOU8 8Odlum dlthlOnlte, 8tlV~ eOid8, and moderately 8trOw br8e8. Under mild aoetylatlon oondltlon8 they ruffered re-aromcrtlutlon, aooompanled in part B C-O bond fl88lon and aoetyl rearzangerent.

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