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Stable free radicals. 9. Magnesium and other metal halide complexes of pyridinyl diradicals

✍ Scribed by Kosower, Edward M.; Hajdu, Joseph; Nagy, Janos B.

Book ID: 119961100
Publisher: American Chemical Society
Year: 1978
Tongue: English
Weight: 979 KB
Volume: 100
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00472a025

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## Abstract The preparation and the ESR. spectra of a 1 : 2 complex of Mg^2+^ with the radical anion of glyoxal‐bis‐N‐__t__‐butylimine (GLI) are reported. The ESR. spectrum of Mg(GLIR)~2~ in 2‐methyl‐tetrahydrofuran at −165° is interpreted as due to a randomly oriented molecular triplet. The magnet