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Stable [Fe3-μ-(CO)2(CO)6-μ3-S][Fe(CO)3-μ-S2C6H12] complex with unusual octacoordinated iron

✍ Scribed by B. I. Kolobkov; A. I. Nekhaev; G. G. Aleksandrov; M. T. Tashev; Kh. B. Dustov; A. Ya. Sideridu


Book ID
112449448
Publisher
Springer
Year
1987
Tongue
English
Weight
53 KB
Volume
36
Category
Article
ISSN
1573-9171

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✍ W. Petz; F. Weller; A. Barthel; C. Mealli; J. Reinhold 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 253 KB 👁 1 views

The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3±n (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri