The kinetics of chlorine transfer from CHzC12, CHC13, cc4, and CCI3CN to the triethylsilyl radical was studied in the liquid phase by a competitive method. Br abstraction from 1- bromopentane was used as a reference. The following Arrhenius parameters were determined: 40 f 0.10 1.11 f 0.18 303-343
Stable and Metastable Phase Diagram of the Two-Component System (CH 3 ) 3 CCl−(CH 3 )CCl 3 : An Example of Crossed Isodimorphism
✍ Scribed by Pardo, Luis C.; Barrio, María; Tamarit, Josep Ll.; Negrier, Philippe; López, David O.; Salud, Josep; Mondieig, Denise
- Book ID
- 126258559
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 109 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0022-3654
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## Abstract Relative rate techniques were used to study the title reactions in 930–1200 mbar of N~2~ diluent. The reaction rate coefficients measured in the present work are summarized by the expressions __k__(Cl + CH~2~F~2~) = 1.19 × 10^−17^ __T__^2^ exp(−1023/T) cm^3^ molecule^−1^ s^−1^ (253–553
The absolute UV absorption cross sections of CF3CC1202, CFJCHF02, CFC12CH202, and CFZCICH20, have been measured in the gas phase at 298 K in the range 200-290 nm using the flash-photolysis technique. CF,COCl has been identified as a product in the system involving the self-reaction of CF$C1202.