Stable Adducts of a Dimeric Magnesium(I) Compound
✍ Scribed by Shaun P. Green; Cameron Jones; Andreas Stasch
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 448 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Review: 164 refs.
## Abstract **The odd couple**: A dimeric magnesium(I) complex acts as a facile and selective two‐center/two‐electron reductant towards a series of unsaturated substrates (see scheme; Ar=2,6‐__i__Pr~2~C~6~H~3~, Ad=1‐adamantyl). The novel reduced or reductively coupled products obtained from these r
The reaction of ethoxyxcarbonyl isothiocyanate with water isothiocyanate. Compound 2 can be isolated chromatographically, but it is slowly oxidized when allowed to stand in in the absence of a solvent has yielded the new compound [EtO 2 CN=CS 2 C{N(H)CO 2 Et}{S 2 CN(H)CO 2 Et}] (1) in 76% the open a