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Stabilization of tris(trifluoromethyl)borane in complexes with primary, secondary and tertiary amines. Crystal and molecular structure of (CF3)3B·NHEt2 and (CF3)3B·NH2Et

✍ Scribed by D.J. Brauer; H. Bürger; F. Dörrenbach; B. Krumm; G. Pawelke; W. Weuter


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
861 KB
Volume
385
Category
Article
ISSN
0022-328X

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Trimethylamine-bis(trifluoromethyl) boranes R(CF 3 ) 2 B ´NMe 3 (R = cis/trans-CF 3 CF=CF (1/2), HCºC (3), H 2 C=CH (4), C 2 H 5 (5), C 6 H 5 CH 2 (6), C 6 F 5 (7), C 6 H 5 (8)) react with NEt 3 ´3 HF depending on the nature of R at 155±200 °C under replacement of the trimethylamine ligand to form