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Stabilization of the Pentacoordination of Phosphorus by Tridentate Ligands

✍ Scribed by Prof. Dr. Dieter Hellwinkel; Dipl.-Chem. Wolfgang Krapp


Book ID
101550559
Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
218 KB
Volume
13
Category
Article
ISSN
0044-8249

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Hypervalent pentacoordinate boron compounds (10-B-5) have been postulated as transition states in S N 2-type reactions at a boron atom. For example, the reaction of the [BH 3 -CO] complex with NMe 3 [2] as well as the intramolecular bond switch at the boron atom in compounds bearing a van Koten typ