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Stabilization of polyheteroatomic aza and phospha analogs of cyclobutadiene and benzene

✍ Scribed by M. N. Glukhovtsev; B. Ya. Simkin; V. I. Minkin


Book ID
104781578
Publisher
Springer US
Year
1988
Tongue
English
Weight
472 KB
Volume
24
Category
Article
ISSN
0009-3122

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Completely different effects on the stability of cyclobutadiene are found upon replacement of C with N or P. Whereas in the phospha derivatives the cyclobutadiene structure is less stable than the tetrahedrane, and the barrier to valence isomerization is reduced, the exchange of N for C increases th

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