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Stability of the Metal Configuration in Chiral-at-Metal Half-Sandwich Compounds

โœ Scribed by Henri Brunner


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
454 KB
Volume
2001
Category
Article
ISSN
1434-1948

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Condensation of (R)-2-aminobutanol with salicylaldehyde 3b showed a structural peculiarity. The unit cell of these complexes contained diastereomers with the same and 2-pyrrolecarbaldehyde gave the chiral chelate ligands HLL 1 \* and HLL 2 \*, respectively. The diastereomeric configuration at the ca