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Stability of PhCH2CH2ĊHX (X = H, CF3, Me, CO2Me) Radicals

✍ Scribed by Rashid G. Gasanov; Tamara T. Vasilieva; Sergei I. Gapusenko; Yurii A. Borisov


Book ID
111729331
Publisher
Royal Society of Chemistry
Year
1991
Tongue
English
Weight
245 KB
Volume
1
Category
Article
ISSN
0959-9436

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All arrangements and procedures for steady-state and time-resolved ESR were as described in [4]. The radicals Me,C and Me3C02CCH, were generated by photolysis of the corresponding disubstituted ketones. These undergo type-I cleavage from a short-lived triplet state followed by a fast decarbonylation