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Stability of Metal−Organic Complexes in Acetone− and Methanol−Water Mixtures

✍ Scribed by Xue, Yuan; Traina, Samuel J.; Hille, Russ


Book ID
126052250
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
368 KB
Volume
30
Category
Article
ISSN
0013-936X

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Solvolysis of benzoyl cyanides in methan
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Rate constants for solvolysis of bensoyl cyanides in methanol-acetonitrile and methanol-acetone mixtures were determined. Effects of substituent and solvent indicated that the reaction preceeds via an associative SN2 mechanism. Benzoyl cyanide is known to behave like an acyl halide rather than a k