Peroxotungstic acid and quaternary ammonium peroxotungstic salts when complexed to organophosphorus(V) ligands exhibit enhanced reactivity and selectivity in the epoxidation of unsaturated alcohols with hydrogen peroxide. The organophosphorus ligands contain the phosphoryl O=P= subunit as complexing
Stability of crude ligninases: Effect of different hydrogen peroxide concentrations in the presence of aromatic alcohols
✍ Scribed by Julio Silva Araujo Neto; Sérgio Hélio Kling
- Publisher
- Springer-Verlag
- Year
- 1993
- Tongue
- English
- Weight
- 182 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0951-208X
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✦ Synopsis
In absence of veratryl alcohol (VA), Phanerochaete chrysosporium ligninases were extensively inactivated by H202 concentrations as low as 5.0 ~M (i hr exposure time, pH 4.5, 38°C). In the presence of 2.5 mM VA (but not 2.5 mM benzyl alcohol), protection occurred below 500 ~M H202.
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