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Stability of cis and trans amide bond conformations in polypeptides

✍ Scribed by Tonelli, Alan E.


Book ID
121234671
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
323 KB
Volume
93
Category
Article
ISSN
0002-7863

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Trans-cis amide bond isomerization in fu
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The 1 H NMR study of fulleroproline derivative Ac-Fpr-OtBu and its Pro analogue Ac-L-Pro-OtBu over a range of temperatures in toluene-d 8 solution has enabled the comparison of their equilibrium and activation parameters for the trans/cis interconversion around the amide partial double bond.