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Stability of carbon-bonded anionic .sigma. complexes. 3. Decomposition in aqueous acidic media

โœ Scribed by Renfrow, R. A.; Strauss, M. J.; Terrier, F.


Book ID
126294477
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
617 KB
Volume
45
Category
Article
ISSN
0022-3263

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Dry carbonic acid has recently been shown to be kinetically stable even at room temperature. Addition of water molecules reduces this stability significantly, and the decomposition (H2CO3 + nH2O --> (n+1)H2O + CO2) is extremely accelerated for n = 1, 2, 3. By including two water molecules, a reactio