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Stability of almandine in the system FeO-(Fe2O3)-Al2O3-SiO2-(H2O) at elevated pressures

✍ Scribed by I. Keesmann; S. Matthes; W. Schreyer; F. Seifert


Publisher
Springer
Year
1971
Tongue
English
Weight
816 KB
Volume
31
Category
Article
ISSN
0010-7999

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✦ Synopsis


Almandine, although decomposing in the presence of metallic iron into the anhydrous subsolidus assemblage fayalite + ferrocordierite + hereynite solid solution at low pressures, melts incongruently to hercynitess -~ quartz + liquid at 10 kb. At pressures between about 12 and 20 kb the products of incongruent melting are hercynitess + liquid only, and at still higher pressures almandine melts congruently. For the intermediate pressures between 2 and 10 kb not investigated a sequence of probable breakdown and melting relations involving the phases ferrocordierite, fayalite, hercynitess, quartz, and liquid is derived through Sehreinemakers' analyses.

The lower temperature stability limit of almandine in the presence of water at low oxygen fugacities and pressures of 15 to 20 kb lies between 550 ~ and 600~ as at low pressures. It is marked, however, by the breakdown to a hydrous assemblage involving ehloritoid and the new phase aluminous deerite. Since the anhydrous melting at these pressures occurs between 1300 ~ and 1400 ~ C, the thermal stability range of almandine increases drastically with pressure. Its upper breakdown limit shows in principle a similar behavior as those of other garnet end members.


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