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Stability of 4H- and 12R-type titanium sulphide structures

โœ Scribed by Masanobu Saeki; Mitsuko Onoda; Zheng Tan

Book ID
116015339
Publisher
Elsevier Science
Year
1985
Weight
830 KB
Volume
108
Category
Article
ISSN
0022-5088

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The second largest molecule so far dealt with by ab initio methods is the tetrameric Al^1^ compound [__t__Bu~3~SiAl]~4~. The calculations yielded structure parameters that are in agreement with those of related compounds, and showed that, above all, the lack of ฯ€ backbonding in the monomer explains