Stability Constants of Magnesium Porphyrin-Pyridine Complexes. Solvent and Substituent Effects 1
β Scribed by Storm, Carlyle B.; Corwin, Alsoph H.; Arellano, Robert R.; Martz, Mark; Weintraub, Ronald
- Book ID
- 127298567
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 917 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A broad study of the 59C0 N M R of cobalt(1II) porphyrin complexes with axial amine ligands in a variety of solvents is reported. The data are presented in tabular form, as are the numerical correlations of chemical shift, 6, a d line width, ol/\*, using the Kamlet-Taft equation. The dependence of 6
## Abstract The acidity constants of the six thienylβ and the three phenylβpyridines, and the stability constants of the corresponding Cu^2+^ 1:1 complexes were determined in aqueous solution (__I__ = 0.1, NaCIO~4~; 25Β°). The basicity of the pyridyl group is increased by a shift of a thienyl or phe