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Stability constants of diaza-crown-ether complexes of univalent metal ions and free energies of transfer of ligand and complexes from acetonitrile to several solvents

✍ Scribed by B.G. Cox; P. Firman; H. Horst; H. Schneider

Book ID
108428714
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
448 KB
Volume
2
Category
Article
ISSN
0277-5387

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Free energies of transfer from water to
Free energies of transfer from water to non-aqueous solvents of univalent (2,2,2) cryptand and 18-crown-6 complexes
✍ B.G. Cox; P. Firman; J. Garcia-Rosas; H. Schneider πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 242 KB

A complexation scheme involving a conformational equilibrium of the ligand is proposed to explain the difference in free energies of transfer between metal complex and ligand from water to non-aqueous solvents. In a recent paper Abraham and Ling' have reported the thermodynamic parameters of transf