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Stability and Three-Dimensional Aromaticity of closo -Monocarbaborane Anions, CB n -1 H n- , and closo -Dicarboranes, C 2 B n -2 H n

✍ Scribed by Schleyer, Paul von Ragué; Najafian, Katayoun

Book ID
124098358
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
304 KB
Volume
37
Category
Article
ISSN
0020-1669

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## Abstract The first primary 2‐aminocarba‐__closo__‐dodecaborates [1‐R‐2‐H~2~N‐__closo__‐CB~11~H~10~]^−^ (R=H (1), Ph (2)) have been synthesized by insertion reactions of (Me~3~Si)~2~NBCl~2~ into the trianions [7‐R‐7‐__nido__‐CB~10~H~10~]^3−^. The difunctionalized species [1,2‐(H~2~N)~2~‐__closo__