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Stability and symmetry of the 8,9-dehydro-2-adamantyl cation

โœ Scribed by Baldwin, John E.; Foglesong, William D.


Book ID
127229677
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
221 KB
Volume
89
Category
Article
ISSN
0002-7863

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13C nmr of aryl substituted cations: the
โœ Donald G. Farnum; Thomas P. Clausen ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 211 KB

A series of aryl substituted Coates and 2-adamantyl cations were generated and their 'jC NMR spectra determined to be consistent with sigma-bridged structures for the former, and unbridged structures for the latter. Of all the cations mentioned in the literature, the Coates cation (1) and some deriv