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Stabilisation and reactions of aliphatic radical cations produced by fast electron irradiation in solid argon matrices

โœ Scribed by Feldman, Vladimir; Sukhov, Fedor; Orlov, Aleksei; Tyulpina, Irina


Book ID
121500148
Publisher
Royal Society of Chemistry
Year
2003
Tongue
English
Weight
136 KB
Volume
5
Category
Article
ISSN
1463-9076

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๐Ÿ“œ SIMILAR VOLUMES


Studies on Radical Cations I. Molecular
โœ Thomas Bally; Edwin Haselbach; Zuzana Lanyiova; Peter Baertschi ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 780 KB

## Abstract ฮณโ€Irradiation of tris (methylidene)โ€cyclopropane (โ€˜[3]radialeneโ€™) **1** in a rigid electron scavenging matrix (butylchoride/iโ€pentane, 1:1) at 77 K leads to formation of its molecular cation **1**^+^. Slight softening of the matrix by a temperature increase of 3โ€“5 K results in formation