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Stabile Triaziridine

✍ Scribed by Prof. Dr. Gerd Kaupp; Dr. Oswald Dengler; Prof. Dr. Klaus Burger; Silvia Rottegger

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
243 KB
Volume
97
Category
Article
ISSN
0044-8249

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## Stable Pyramidal Configurations at the Nitrogen Atoms of Dialkyl-and Trialkyl-triaziridines Stereochemical features of the recently synthesizcd nine samples of di-and trialkyl-triaziridines, namely the 1 ,kyclopentylen-(series a) and the two stereoisomcrs or the diisopropyl derivatives (series

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Table I . Absolute (E,,,, [Hartree]) and relative energies (E,,, [kcal/mol]) for neutral ( I ) and ionized ( la) aminoacetylene and for some isomers and dissociation products calculated at the 6-31G(d)//6-31G(d) [lo] level of theory. .84557 -131.87126 -131.724450 -131.775308 -130.982298 [b] -131.74