Square-Wave Voltammetry of Quasi-Reversible CE Reactions at Spherical Microelectrodes
✍ Scribed by Fernando Garay; Milivoj Lovrić
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 292 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1040-0397
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## Abstract The reduction process of monoprotic weak acids (lactic and acetic acid, and dihydrogen phosphate ion) and mixtures of a strong and a weak acid (perchloric and one of the above weak acids) have been investigated by square‐wave voltammetry (SWV) at a platinum microelectrode 12.5 μm radius
A method to monitor the progress of homogeneous chemical reactions using square-wave voltammetry is presented. The square wave voltammogram of a single species may be approximated to a high degree of accuracy with a Gaussian peak. Overlapping voltammograms may be deconvoluted to yield the contributi