Square wave electrolysis IV. Results and discussion
✍ Scribed by M. D. Wijnen; W. M. Smit
- Book ID
- 104586153
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 844 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0165-0513
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✦ Synopsis
Abstract
The cyclic potential‐step method and the cyclic current‐step method are applied to two Red/Ox systems. Values of the standard exchange current density and of the transfer coefficient of both the ferro‐ferri system in 1__M__ H~2~SO~4~ and the ferrocyanide‐ferricyanide system in 1__M__ KCl are determined. The results obtained by the two methods are in good agreement with each other. A comparison is made with data obtained by other methods, mentioned in the literature.
📜 SIMILAR VOLUMES
## Abstract The experimental setups required for the cyclic potential‐step and cyclic current‐step methods are thoroughly discussed. Attention is paid to the following subjects: conditions for linear diffusion, reference electrode, potentiostatic conditions, time‐symmetry of the applied square wave
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