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SP−PLP−EPR Study of Chain-Length-Dependent Termination in Free-Radical Polymerization of n -Dodecyl Methacrylate, Cyclohexyl Methacrylate, and Benzyl Methacrylate: Evidence of “Composite” Behavior †

✍ Scribed by Buback, Michael; Müller, Elena; Russell, Gregory T.

Book ID: 127227094
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 163 KB
Volume: 110
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp054606r

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## Abstract Termination kinetics of methyl methacrylate (MMA) bulk polymerization has been studied via the single pulsed laser polymerization–electron paramagnetic resonance method. MMA‐__d__~8~ has been investigated to enhance the signal‐to‐noise quality of microsecond time‐resolved measurement of