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Spotlights on our sister journals: Chem. Eur. J. 36/2007

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 192 KB
Volume: 2007
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200790096

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Holey phosphines! The end capping of triethynylphosphine with bulky groups results in the creation of ligands with a large cavity in which the phosphorus lone-pair electrons are located. The novel coordination properties of these ligands lead to a rate-accelerating effect in the rhodium-catalyzed hy