Theoretical studies on the gas-phase nuc
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Wang Ki Kim; Wang Sun Ryu; In-Suk Han; Chang Kon Kim; Ikchoon Lee
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Article
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1998
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John Wiley and Sons
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English
β 167 KB
π 2 views
Gas-phase nucleophilic substitution reactions of Y-benzyl chlorides with X-phenoxide and Xthiophenoxide nucleophiles were investigated theoretically using the PM3 semi-empirical MO method. The Leffler-Grunwald rate-equilibrium and BrΓΈnsted correlations predict that the degree of bond formation in th