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Spontaneous conversion of 2-azido-3-nitropyridines to pyridofuroxans

✍ Scribed by Elisa Leyva; Denisse de Loera; Rogelio Jiménez-Cataño

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
205 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis

Several pyridofuroxans were obtained by spontaneous N 2 elimination from the corresponding 2-azido-3nitropyridines. In this particular case, the presence of nitrogen in the pyridine ring must facilitate a cyclic extrusion mechanism. The pyridofuroxans prepared in this study did not present tautomerism as evidenced by NMR.

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