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Spontaneous [2,3]-sigmatropic rearrangement of s-arylthiosulfonium ylids formed in the reaction of arylsulfenyl chlorides with methylthiolyiethyltrimethylsilane

✍ Scribed by Paul G. Gassman; Takashi Miura

Book ID: 104243460
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 239 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92343-3

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✦ Synopsis

SLmmlary: A new [2,3]-sigmatropic rearrangement of thiosulfonium ylids yields ortho-methylthiomethylthiophenols. The ylids were generated through the cleavage of a C-Si bond with chloride anion.

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