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Splitting of states by electron phonon interaction: Cr3+ in alums

✍ Scribed by K.N. Shrivastava

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
233 KB
Volume
22
Category
Article
ISSN
0009-2614

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✦ Synopsis

The phenomenon of splitting of states of CI 3t by the electron-phonon interaction is studied. it is found that the puameter describing the phenomenon decreases successively in the order NH4-, K-, Rb-, Csalum. The temperature dependence of the phenomenon is therefore smaller for heavier ligands.

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Crystal field effects and electron–phonon interaction in K2LiAlF6:Cr3+
✍ A.M. Reisz; M.G. Brik; C.N. Avram; N.M. Avram πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 161 KB

The crystal field effects and electron-phonon interaction in K 2 LiAlF 6 :Cr 3 + elpasolite crystal were studied using the exchange charge model (ECM) of crystal field and harmonic approximation of lattice vibrations. The crystal field parameters (CFP) and energy level scheme for the [CrF 6 ] 3 Γ€ cl