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Splitting of Gd+3 terms in the crystal field of CaF2

✍ Scribed by M. Nerenberg; M. Schlesinger


Book ID
107984686
Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
133 KB
Volume
26
Category
Article
ISSN
0375-9601

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Overlap and covalent contributions to th
✍ F. Anisimov; R. Dagys πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 395 KB

## Abstract The crystal field splittings in CaF~2~:Tm^2+^ were calculated within the framework of the complex (TmF~8~)^6βˆ’^. By separating the overlap from covalent contributions, the overlap effects were found to dominate. It is shown that ligand‐ligand overlap effects are important. On the contrar