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Splitting CC Double Bonds with Sodium Hydrazide

✍ Scribed by Doz. Dr. Th. Kauffmann; Dipl.-Ing. H. Henkler; Dr. C. Kosel; cand. Ing. E. Rauch; Jutta Schulz; Reingard Weber


Publisher
John Wiley and Sons
Year
1962
Tongue
English
Weight
217 KB
Volume
1
Category
Article
ISSN
0044-8249

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Quaternized Ξ³-amino alcohols 5 derived from ternary bond in a Grob-type fragmentation and highly functionalized oxetanes 7 by intramolecular substitution. iminium salts 2 are stereospecifically converted into both unsaturated aldehydes/ketones 6 with a (Z)-CΟͺC double Scheme 1 Typical methods used f