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Spiro[Adamantane-2,1′-Cyclobutane-2′,3′-Dione]: (Preliminary communication)

✍ Scribed by Hans Wynberg; S. Reiffers; J. Strating


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
116 KB
Volume
89
Category
Article
ISSN
0165-0513

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## Abstract 1,2__endo__‐Trimethylenenorbornane **(1)** in the presence of aluminium bromide in carbon disulfide at −60° isomerizes at a much higher rate than its 2__exo__‐isomer **2** to 2__endo__, 6__endo__‐trimethylenenorbornane **(3)** as the sole product. By consequence, the hydrocarbon **2** b