Abstraet--A continuum model describing the spinodal decomposition of polymer blends under externally applied shear has been developed. Numerical simulations were conducted for two-dimensional Couette flow. The morphology of the resulting polymer blend was established by competition between diffusion
Spinodal decomposition in binary fluids under shear flow
โ Scribed by Yanan Wu; Hana Skrdla; Turab Lookman; Shiyi Chen
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 978 KB
- Volume
- 239
- Category
- Article
- ISSN
- 0378-4371
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โฆ Synopsis
We discuss the effects of shear rates on the structure, rheology and kinetics of phase separation in binary fluids through numerical Langevin simulations in both two-and three-dimensions. Our major findings are as follows: (1) shear flow distorts the isotropy properties in normal spinodal decomposition. Under stronger shear, a string phase appears; (2) domains grow differently in directions parallel and perpendicular to the flow direction; (3) excess shear viscosities due to shear flow have a characteristic peak as a function of shear rates. We compare our findings with the experimental data and simulation results which do not incorporate hydrodynamics.
๐ SIMILAR VOLUMES
We use a lattice Boltzmann scheme to study the spinodal decomposition of a simple binary mixture and of a structured fluid with lamellar order. In the case of the binary mixture hydro-1 2 For a lameldynamic effects change the growth exponent from the diffusive value z 3 to z = 3" lar fluid hydrodyna