Spinning sidebands (SSBs) in the MAS NMR spectrum of a polycrystalline solid are related to the principal values of the chemical shift or quadrupole coupling tensors. At present, 2D methods are widely used to sort out the SSBs for each isotropic peak. Here a simple and efficient method for separatin
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Spinning-Sideband-Pattern Deviations in Cross-Polarization MAS NMR Spectra
β Scribed by G. Jeschke; G. Grossmann
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 527 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1064-1858
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The cobaltocenium ions [Cp Ε 2 Co] C , [Cp Ε CpCo] C , [Cp 2 Co] C and [ EtC 5 H 4 2 Co] C Cp Ε D C 5 Me 5 ; Cp D C 5 H 5 were studied by 13 C cross-polarization magic angle spinning NMR spectroscopy. The ring carbon signals of [Cp Ε 2 Co] C [PF 6 ] and [Cp Ε CpCo] C [PF 6 ] showed splitting patter