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Spinning-frequency-dependent linewidths in 1H-decoupled 13C magic-angle spinning NMR spectra

โœ Scribed by Toshihito Nakai; Charles A. McDowell

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
453 KB
Volume
227
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The broadenings observed in "C MAS NMR spectra, which depend on the sample-spinning speed, were studied, using polycrystalline adamantane. Not only was a monotonic increase of the linewidths with the increase of the spinning frequency observed, but also a novel resonant feature was found. The phenomena were interpreted as originating from rotary-resonance "C-'H recoupling.

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