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Spinel Solid Solutions in the Li–Fe–Mn–O System

✍ Scribed by Tomáš Grygar; Petr Bezdička; Petr Vorm; Neli Jordanova; Petr Krtil

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
443 KB
Volume
161
Category
Article
ISSN
0022-4596

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✦ Synopsis

The ranges of Li+Fe+Mn composition in which single-phase microparticulate spinel oxides are formed by heating in air were determined. The aim was to reevaluate previously published reports on binary solid solutions between LiFe 5 O 8 and Li+Mn+O spinels by covering the whole possible range of (Li, Fe, Mn) 3 O 4 spinels with Mn valence higher than 3. To sensitively detect possible heterogeneity of the elemental distribution or phase composition, chemical and X-ray powder di4raction analyses were used, temperature dependence of magnetic susceptibility was obtained for samples rich in Fe, and electrochemical reductive dissolution was studied by means of voltammetry of microparticles. Instead of a continuous series of solid solutions, three regions were found with di4erent dependence of lattice parameters on elemental composition. A region of nonuniform solid solutions was found at Fe/(Fe؉Mn)> 0.4 and Mn valence >3.2.

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