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Spinel electrodes for lithium batteries — A review

✍ Scribed by M.M. Thackeray; L.A. de Picciotto; A. de Kock; P.J. Johnson; V.A. Nicholas; K.T. Adendorff

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
490 KB
Volume
21
Category
Article
ISSN
0378-7753

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✦ Synopsis

This paper briefly reviews recent electrochemical data of several transition-metal oxide and sulphide spine1 compounds of general formula A[B2]X4 that have been employed as cathode materials in both roomtemperature and high-temperature (400 "C) lithium cells. Particular attention is given to the performance of the oxide spinels M304 (M = Fe, Co, Mn) that have like A-and B-type cations, the lithium spinels Li[M2]04 (M = Ti, V, Mn) and LiFesOs, and the thiospinels CuCo& and CuTi& Reaction processes and the structural characteristics of the reaction products are highlighted.

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