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Spin Trapping Studies of Amine-Stabilized Trialkylborane Free Radical Initiator Systems: Kinetics and Mechanism

โœ Scribed by Anne C. Moran; Natalia V. Lebedeva; Sabine Richert; Malcolm D. E. Forbes

Book ID
106220822
Publisher
Springer Vienna
Year
2011
Tongue
English
Weight
395 KB
Volume
41
Category
Article
ISSN
0937-9347

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๐Ÿ“œ SIMILAR VOLUMES

Free radical initiation mechanisms in th
Free radical initiation mechanisms in the polymerisation of diethyl fumarate and diethyl maleate studied by the nitroxide trapping technique
โœ W. Ken Busfield; Ian D. Jenkins; Kirstin Heiland ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 580 KB

The radical trapping technique employing the stable nitroxide 1 as a scavenger has been used to study the reaction of t-butoxyl radicals with diethyl fumarate and with diethyl maleate. The major pathway with both monomers is hydrogen abstraction from the ester alkyl groups by t-butoxyl radicals. The