Spin trapping of intermediate radicals in the solid state gamma radiolysis of perfluoropolyethers
โ Scribed by A. Faucitano; A. Buttafava; F. Martinotti; G. Caporiccio; C.T. Viola
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 71 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0022-1139
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๐ SIMILAR VOLUMES
Tl~e primary radicals produced during radiolysis of methanol have been delcctcd by a spin trapping method. The electron spin resonnnce spectra b'xre directly observed during radiolysis of r-BuWO solutions wirh a 3 hlcV electron beam from an accclcrator. 7l1csc showed thal mcthoxy, CHaOg, and hydrow
## Abstract A series of substituted 4โmethylphenols **1** and **2** was oxidized with PbO~2~ in the presence of nitroso compounds **3**โ**10**. The formation of adducts of benzyl radicals with the nitroso spin traps in the reaction mixture was established, suggesting the abstraction of an Hโatom fr