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Spin trapping in biological systems. Oxidation of the spin trap 5,5-dimethyl-1-pyrroline-1-oxide by a hydroperoxide-hematin system

✍ Scribed by Robert A. Floyd; Lailing M. Soong


Book ID
118311912
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
276 KB
Volume
74
Category
Article
ISSN
0006-291X

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A chiral spin trap, 5,5-dimethyl-3-phenyIpyrroline-l-oxide (3, and several hydroxylamines were synthesized. The structures and conformations of these compounds were investigated mainly by 'H NMR spectroscopy. This spin trap was used to trap carbon-and oxygen-centered radicals. The corresponding hydr