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Spin-transition behaviour of transition metal complexes with 2,6-bis-(benzimidazol-2′-yl)-pyridine induced by deprotonation of the complex

✍ Scribed by M. Enamullah; W. Linert; V. Gutmann; R. F. Jameson

Publisher
Springer Vienna
Year
1994
Tongue
English
Weight
514 KB
Volume
125
Category
Article
ISSN
0026-9247

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Structure and Highly Stereoselective Formation of 1:2 Metal-to-Ligand complexes with triamine 2,6-bis(pyrolidin-2-yl)pyridine. meso-[2,6-bis(pyrrolidin-2yl)pyridine]nickel(II) (meso-[Ni(bpp)2]2+), a Metal Complex with S4 Symmetry
✍ Klaus Bernauer; François Gretillat; Helen Stoeckli-Evans; Ruth Warmuth 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 German ⚖ 618 KB

The X-Ray structures of the 1:l copper(I1) complexes with racemic and optically active (+)-(R,R)-(2,6bis(pyrro1idin-2-y1)pyridine ((+)-bpp; (+)-I) were determined. Whereas the perchlorate 1 of the racemic complex contains the monomeric units with perfect C, symmetry, the sulfate of the optically act