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Spin state transformations of a 3d ion in the pyramidal environment and under lattice distortions

✍ Scribed by Zhitlukhina, E S; Lamonova, K V; Orel, S M; Lemmens, P; Pashkevich, Yu G


Book ID
125444308
Publisher
Institute of Physics
Year
2007
Tongue
English
Weight
836 KB
Volume
19
Category
Article
ISSN
0953-8984

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Lattice trapping of metastable quintet s
✍ Harold A. Goodwin; Kristian H. Sugiyarto πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 393 KB

The 'Tz% 'A, spin transition in [ Fe( bpp),][ BF412 (bpp= 2,6-bis( pyrazol-3-yl)pyridine) is abrupt and complete and shows hysteresis with the transition temperatures r,r = 173 K and T,t = 183 K. Rapid cooling of the sample causes the freezing-in of metastable quintet state species at low temperatur