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Spin relaxation in high-spin iron(III) complexes of tetraphenylporphine

โœ Scribed by Toshie Ohya; Mitsuo Sato


Book ID
113283851
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
216 KB
Volume
76
Category
Article
ISSN
0168-583X

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Photoexcitation and Relaxation Dynamics
โœ Cristian Enachescu; Andreas Hauser; Jean-Jacques Girerd; Marie-Laure Boillot ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 394 KB

## Abstract The photophysical properties of the ferric catecholate spinโ€crossover compounds [(TPA)Fe(Rโ€Cat)]X (TPA=tris(2โ€pyridylmethyl)amine; X=PF~6~^โˆ’^, BPh~4~^โˆ’^; Rโ€Cat=catecholate dianion substituted by R=NO~2~, Cl, or H) are investigated in the solid state. The catecholateโ€toโ€iron(III) chargeโ€