Spin polarized photoelectrons from CO2 and N2O
✍ Scribed by U. Heinzmann; F. schäfers; B.A. Hess
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 436 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0009-2614
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## Abstract We report on the gas phase reactions of small Fe^+^~__n__~ clusters (__n__ = 2–10) with O~2~, N~2~O and CO~2~ in an FT‐ICR mass spectrometer. Under our experimental conditions, clusters of all sizes reacted readily with O~2~ and all but the dimer reacted with N~2~O. Only the smallest Fe
Molecules with multiple bonds are challenging for computations of nuclear spin-spin coupling constants. Tbis can be referred to the asserted importance of non-contact mechanisms, to sharp geometry variations as well as to the handling of the electronic structure problem. We employ a recently develop