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Spin-orbit corrections to the indirect nuclear spin-spin coupling constants in XH4(X = C, Si, Ge, and Sn)

✍ Scribed by Sheela Kirpekar; Hans Jørgen Aagaard Jensen; Jens Oddershede


Publisher
Springer
Year
1997
Tongue
English
Weight
890 KB
Volume
95
Category
Article
ISSN
1432-2234

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The density dependence of J13c-n in 13CH4 has been accurately measured in a methane sample containing thenatural amotmt of ~3CH4. A linear increase of J~3c-n with increasing density has been found. The total variation over a density interval from 0-575 amagat is 0.24 Hz.