The firequency depmdence of TJ\_ iu glycerol, at frequencies below 6 MHz, fnd&ates that thcr major contributkm to the frequency dependent xAaxatIon is due to the Intermolecular S&exaction. The 8eI.f diffusion con&ant is detezmined to be (1.9 t 0.1) x lOwa cm?sec at 2WΒ°C. ## Recent measurements [X]
Spin-lattice relaxation in Co complexes of low symmetry
β Scribed by Steve C.F Au-Yeung; Richard J Buist; Donald R Eaton
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 978 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0022-2364
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π SIMILAR VOLUMES
A generalization of the modified Solomon-Bloembergen-Morgan (MSBM) equations has been derived in order to describe paramagnetic relaxation enhancement (PRE) of paramagnetic complexes characterized by both a transient (β¬ t ZFS ) and a static (β¬ s ZFS ) zero-field splitting (ZFS) interaction. The new
The slow-motion theory of nuclear spin relaxation in paramagnetic low-symmetry complexes is generalized to comprise arbitrary values of S. We describe the effects of rhombic symmetry in the static zero-field splitting (ZFS) and allow the principal axis system of the static ZFS tensor to deviate from