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Spin-Labeling in High-Field EPR

โœ Scribed by Alex I. Smirnov

Publisher
John Wiley and Sons
Year
2003
Weight
65 KB
Volume
34
Category
Article
ISSN
0931-7597

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High-field spin-label EPR of lipid membr
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High-field EPR of spin-labelled lipid chains has proved to be an extremely productive means for biophysical investigations of phospholipid bilayer membranes. Results on the following three topics are reviewed: 1. Non-axial ordering of lipid chains in cholesterol-containing membranes; 2. Transmembra

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The high-field (i.e., 94 GHz) membrane EPR spectra of lipids spin labeled in their fatty acid chains have been simulated by using two limiting motional models. The aim was to identify the dynamic origin of the residual (g(xx) - g(yy)) anisotropy observed in the nonaxial EPR spectra of cholesterol-co

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## Abstract __The isolation, structural characterization, and electronic properties of two sixโ€coordinated chloromanganese (III) complexes, [Mn(terpy)(Cl)~3~] (1) and [Mn(Phterpy)(Cl)~3~] (2), are reported (terpy=2,2โ€ฒ:6โ€ฒ2โ€ฒโ€ฒโ€terpyridine, Phterpy=4โ€ฒโ€phenylโ€2,2โ€ฒ:6โ€ฒ,2โ€ฒโ€ฒโ€terpyridine). These complexes co

Determination of High-Spin Iron(III)โ€“Nit
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## Continuous wave EPR spectra of the nitroxyl signals for four Continuous wave (CW) electron paramagnetic resonance spin-labeled high-spin (h.s.) Fe(III) porphyrins showed partially (EPR) has been used to obtain electron-electron interspin resolved splittings at temperatures near 4 K. Axial ligan